Traditional oxidants also react, including the halogens and oxygen at higher temperatures. In the presence of oxygen, it reacts with cyanide salts. Iridium is the most corrosion-resistant metal known: it is not attacked by acids, including aqua regia. The Vickers hardness of pure platinum is 56 HV, whereas platinum with 50% of iridium can reach over 500 HV. Iridium is extremely brittle, to the point of being hard to weld because the heat-affected zone cracks, but it can be made more ductile by addition of small quantities of titanium and zirconium (0.2% of each apparently works well). Some ambiguity occurred regarding which of the two elements was denser, due to the small size of the difference in density and difficulties in measuring it accurately, but, with increased accuracy in factors used for calculating density, X-ray crystallographic data yielded densities of 22.56 g/cm 3 (0.815 lb/cu in) for iridium and 22.59 g/cm 3 (0.816 lb/cu in) for osmium. The measured density of iridium is only slightly lower (by about 0.12%) than that of osmium, the densest metal known. Despite these limitations and iridium's high cost, a number of applications have developed where mechanical strength is an essential factor in some of the extremely severe conditions encountered in modern technology. This, together with a high shear modulus and a very low figure for Poisson's ratio (the relationship of longitudinal to lateral strain), indicate the high degree of stiffness and resistance to deformation that have rendered its fabrication into useful components a matter of great difficulty. Iridium's modulus of elasticity is the second-highest among the metals, being surpassed only by osmium. It has the 10th highest boiling point among all elements and becomes a superconductor at temperatures below 0.14 K (−273.010 ☌ −459.418 ☏). It is the only metal to maintain good mechanical properties in air at temperatures above 1,600 ☌ (2,910 ☏). Because of its hardness, brittleness, and very high melting point, solid iridium is difficult to machine, form, or work thus powder metallurgy is commonly employed instead. It is thought that the total amount of iridium in the planet Earth is much higher than that observed in crustal rocks, but as with other platinum-group metals, the high density and tendency of iridium to bond with iron caused most iridium to descend below the crust when the planet was young and still molten.Ĭharacteristics Physical properties One troy ounce (31.1035 grams) of arc-melted iridiumĪ member of the platinum group metals, iridium is white, resembling platinum, but with a slight yellowish cast. Similarly, an iridium anomaly in core samples from the Pacific Ocean suggested the Eltanin impact of about 2.5 million years ago. For this reason, the unusually high abundance of iridium in the clay layer at the Cretaceous–Paleogene boundary gave rise to the Alvarez hypothesis that the impact of a massive extraterrestrial object caused the extinction of dinosaurs and many other species 66 million years ago, now known to be produced by the impact that formed the Chicxulub crater. Iridium is found in meteorites in much higher abundance than in the Earth's crust. Important compounds of iridium are chlorides and iodides in industrial catalysis. The dominant uses of iridium are the metal itself and its alloys, as in high-performance spark plugs, crucibles for recrystallization of semiconductors at high temperatures, and electrodes for the production of chlorine in the chloralkali process. 191Ir and 193Ir are the only two naturally occurring isotopes of iridium, as well as the only stable isotopes the latter is the more abundant. Iridium is one of the rarest elements in Earth's crust, with estimated annual production and consumption of only 7.3 tonnes (16 thousand pounds) in 2018. Smithson Tennant, the primary discoverer, named it after the Greek goddess Iris, personification of the rainbow, because of the striking and diverse colors of its salts. Iridium was discovered in 1803 among insoluble impurities in natural platinum. However, corrosion-resistance is not quantifiable in absolute terms: although only certain molten salts and halogens are corrosive to solid iridium, finely divided iridium dust is much more reactive and can be flammable, whereas gold dust is not flammable but can be attacked by substances that iridium resists, such as aqua regia. It is one of the most corrosion-resistant metals, even at temperatures as high as 2,000 ☌ (3,630 ☏). A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of 22.56 g/cm 3 (0.815 lb/cu in) as defined by experimental X-ray crystallography. Iridium is a chemical element it has symbol Ir and atomic number 77.
0 Comments
Leave a Reply. |
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |